Advances in Chemical Physics Volume 159 by Paul Brumer, Stuart A. Rice, Aaron R. Dinner

April 3, 2017 | Physical Chemistry | By admin | 0 Comments

By Paul Brumer, Stuart A. Rice, Aaron R. Dinner

This quantity of Advances in Chemical Physics is devoted, via the individuals, to Moshe Shapiro, previously Canada study Chair in Quantum keep watch over within the division of Chemistry on the college of British Columbia and Jacques Mimran Professor of Chemical Physics on the Weizmann Institute, who passed on to the great beyond on December three, 2013. It focuses totally on the interplay of sunshine with molecules, one in every of Moshe’s longstanding medical loves. although, the big variety of issues coated during this quantity constitutes yet a small a part of Moshe’s immense variety of clinical pursuits, that are good documented in over three hundred examine courses and books.

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H. Kable. “Near threshold photochemistry of propanal. Barrier height, transition state structure, and product state distributions for the HCO channel,” J. Phys. Chem. A, 106: 5817–5827 (2002). 27. Y. Kurosaki. “Energy-flow dynamics in the molecular channel of propanal photodissociation, C2H5CHO -> C2H6+CO: direct ab initio molecular dynamics study,” J. Phys. Chem. A, 110: 11230–11236 (2006). 28. M. A. Buntine, C. Lee, G. F. Metha. “The lowest-lying excited singlet and triplet electronic states of propanal: an ab initio molecular orbital investigation of the potential energy surfaces,” Phys.

42: 467–478 (2009). 20. J. Tadic, I. Juranic, and G. K. Moortgat. “Photooxidation of n-hexanal in air,” Molecules, 6: 287–299 (2001). 21. Y. X. Tang and L. Zhu. “Wavelength-dependent photolysis of n-hexanal and n-heptanal in the 280–330-nm region,” J. Phys. Chem. A, 108: 8307–8316 (2004). 22. J. M. Tadic, I. O. Juranic, and G. K. Moortgat. “Photooxidation of n-heptanal in air: Norrish type I and II processes and quantum yield total pressure dependency,” J. Chem. Soc. , 2: 135–140 (2002). 23. K.

34]. Copyright The Royal Swedish Academy of Sciences. Reproduced by permission of IOP Publishing. All rights reserved. 0 and normalizing the other features’ intensity to it. 5. 1 nm VMP of CH3 NH2 [34, 81, 82]. As mentioned above, the H photofragment yield depends on the SRS vibrational excitation probability, the FC overlap between the vibrational wavefunctions in the ground and excited electronic states, the electronic transition dipole moment and on the photodissociation channel. Since in the VMP process the combined SRS + UV excitation energies are in the ∼43,900–44,530 cm−1 range, the ̃ state is accessed from all the initially prepared vibrational states.

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