Advances in Molecular Structure Research by Jeffrey M. Lemm

April 3, 2017 | Physical Chemistry | By admin | 0 Comments

By Jeffrey M. Lemm

The examine of the constitution of molecular structures is an everlasting region of study. This sequence is dedicated to bringing jointly articles from top employees within the box that draw jointly contemporary theoretical and experimental effects and advances in realizing.

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Van der Waals Solids At the intermolecular level organic-type ligands (viz. ) interact in the same way as organic molecules. This means that ligand-to-ligand interactions are ruled by optimization of van der Waals type interactions and hydrogen bonding. We have demonstrated in several cases that organic ligands control molecular packing arrangements as in the correspond- Metal Clusters 29 ing organic crystals. For example, the relative orientation of the arene ribbons in solid naphthalene, anthracene, coronene, and benzene as well as in some mononuclear arene complexes such as (C6H6)2Cr is of the "herring-bone" type [10].

Discussion . . . . . . . . . . . . . . . . . . . A. van der Waals Solids . . . . . . . . . . . . . . . B. Organometallic Crystal Isomerism . . . . . . . . . . . C. Cation-Anion Interactions . . . . . . . . . . . . . D. Hydrogen Bondings . . . . . . . . . . . . . . . Conclusions and Outlook . . . . . . . . . . . . . . . Acknowledgments . . . . . . . . . . . . . . . . . References . . .

B. Organometallic Crystal Isomerism . . . . . . . . . . . C. Cation-Anion Interactions . . . . . . . . . . . . . D. Hydrogen Bondings . . . . . . . . . . . . . . . Conclusions and Outlook . . . . . . . . . . . . . . . Acknowledgments . . . . . . . . . . . . . . . . . References . . . . . . . . . . . . . . . . . . . ABSTRACT The structures of representative examples of transition metal cluster complexes are discussed in terms of the interplay between intramolecular and intermolecular interactions.

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