By Oleg I. Kolodiazhnyi
Authored through one of many major specialists within the box, this can be the single entire evaluation of chiral organophosphorus compounds, from uneven synthesis to catalysis and pharmacological applications.
As such, this targeted reference covers the chemical historical past in addition to spectroscopical research of phosphorus compounds, and carefully describes all of the numerous man made recommendations for those components. Metal-, organo- and biocatalyzed reactions for the advent of phosphorus are defined as are uneven oxidation and aid tools for the instruction of all attainable oxidation states of phosphorus. The textual content additionally contains commercial purposes for those compounds.
Of specific curiosity to chemists operating within the box of uneven synthesis, in addition to to the pharmaceutical as a result of expanding variety of phosphorous-containing medications
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Extra resources for Asymmetric synthesis in organophosphorus chemistry: synthetic methods, catalysis, and applications
The AC of α-hydroxyphosphonates can be determined by 1 H and 31 P NMR spectroscopy of the mandelate ester derivatives. The observed chemical shifts allow assignment of the AC of the hydroxyphosphonates depending on the position of the phenyl group in the compounds and its shielding eﬀect. Thus, the 1 H NMR spectra of (1S,2R)-diastereomers showed a downﬁeld shift of signals for the O-methyl protons relative to the parent alcohol. 13). 14 Determination of absolute conﬁguration by derivatization of hydroxyphosphonates with MPA.
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